Synthesis of new mono-functionalised tetrathiafulvalene derivatives by reactions of tetrathiafulvalenyllithium with aldehydes and ketones: X-ray crystal structures of TTF-CMe(OH)Fc, TTF-CMe(OMe)Fc and TTF-CH(OMe)TTF (Fc = ferrocenyl)

被引：12

作者：

Bryce, MR

Skabara, PJ

Moore, AJ

Batsanov, AS

Howard, JAK

Hoy, VJ

机构：

[1] Department of Chemistry, University of Durham

来源：

TETRAHEDRON | 1997年 / 53卷 / 52期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/S0040-4020(97)10243-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reactions of tetrathiafulvalenyllithium (TTF-Li) with a range of aldehydes and ketones have been explored for the first time, to provide an efficient route to mono-functionalised TTF derivatives of general formulae TTF-CH(OH)R (R = alkyl, phenyl, tetrathiafulvalenyl and ferrocenyl) and TTF-CR(OH)R' (R = alkyl, phenyl R' = alkyl, phenyl, tetrathiafulvalenyl, ferrocenyl and R-R' = fluorenyl). Subsequent transformations involving the reactive alcohol group of some of these compounds are reported. The structures of the three title compounds have been established by single-crystal X-ray analysis. (C) 1997 Elsevier Science Ltd.

引用

页码：17781 / 17794

页数：14

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