Sodium-mediated manganation: Direct mono- and dimanganation of benzene and synthesis of a transition-metal inverse-crown complex

被引：46

作者：

Carrella, Luca M.

Clegg, William

Graham, David V. ^{[1
]}

Hogg, Lorna M.

Kennedy, Alan R.

Klett, Jan

Mulvey, Robert E.

Rentschler, Eva

Russo, Luca

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

[2] Univ Newcastle, Sch Nat Sci Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

[3] Univ Mainz, Inst Anorgan Chem & Analyt Chem, D-55128 Mainz, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 25期

基金：

英国工程与自然科学研究理事会;

关键词：

alkali metals; arenes; inverse-crown compounds; manganese; metalation; AMIDE CHEMISTRY; MANGANESE(II); MAGNESIUM; CRYSTAL; MOLECULES;

D O I：

10.1002/anie.200700965

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Inside out approach: Twofold deprotonation of benzene by a sodium monoalkyl bisamido manganate(II) reagent derived from BuNa, 2,2,6,6- tetramethylpiperidine, and Mn(CH2SiMe3)2 has produced the first inverse-crown complex in which the transition-metal atoms are incorporated in the host (see X-ray structure, blue N, green Na, purple Mn). Variable-temperature magnetization measurements show that the complex is antiferromagnetic. (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4662 / 4666

页数：5

共 25 条

[1] NEOPENTYL, NEOPHYL, AND TRIMETHYLSILYLMETHYL COMPOUNDS OF MANGANESE - MANGANESE(II) DIALKYLS - MANGANESE(II) DIALKYL AMINE ADDUCTS - TETRA-ALKYLMANGANATE(II) IONS AND LITHIUM-SALTS - MANGANESE(IV) TETRA-ALKYLS [J].