Asymmetric synthesis of tetrahydrofurans and tetrahydropyrans with competitive [1,2]-phenylsulfanyl (PhS) migrations (I): thermodynamic control

被引:11
作者
House, D
Kerr, F
Warren, S
机构
[1] Univ Cambridge, Chem Lab, Cambridge CB2 1EW, England
[2] AstraZeneca R&D Sodertalje, Proc R&D, S-15185 Sodertalje, Sweden
关键词
D O I
10.1039/b005342m
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Triols were prepared in enantiomerically enriched form by a short route that included a Sharpless asymmetric dihydroxylation; treatment of these triols with toluene p-sulfonic acid gave THFs as thermodynamic products.
引用
收藏
页码:1779 / 1780
页数:2
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