Spectroscopic and mass spectrometric methods for the characterisation of metal clusters

被引：68

作者：

Johnson, BFG ^{[1
]}

McIndoe, JS ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

COORDINATION CHEMISTRY REVIEWS | 2000年 / 200卷

关键词：

clusters; characterisation; spectroscopy; mass spectrometry;

D O I：

10.1016/S0010-8545(00)00306-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review covers some of the many spectroscopic and mass spectrometric techniques used to characterise transition metal clusters. Special attention has been paid to recent advances in mass spectrometry, which have allowed the study of compounds previously inaccessible to this method of characterisation. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：901 / 932

页数：32

共 157 条

[1] REACTIONS OF SOLID H2OS3(CO)(10) WITH GASEOUS CO, NH3, AND H2S [J].

AIME, S ;

DASTRU, W ;

GOBETTO, R ;

ARCE, AJ .

ORGANOMETALLICS, 1994, 13 (11) :4232-4236

[2] SYNTHESIS AND CHARACTERIZATION OF THE PARAMAGNETIC [AG13FE8(CO)32]4- TETRAANION - A CUBOCTAHEDRAL AG13 CLUSTER STABILIZED BY FE(CO)4 GROUPS BEHAVING AS 4-ELECTRON DONORS [J].

ALBANO, VG ;

GROSSI, L ;

LONGONI, G ;

MONARI, M ;

MULLEY, S ;

SIRONI, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (14) :5708-5713

[3] VIBRATIONAL-SPECTRA OF THE MU-2-HYDRIDE LIGANDS IN [H4M4(CO)12] (M = OS, RU) [J].

ANSON, CE ;

JAYASOORIYA, UA ;

KETTLE, SFA ;

STANGHELLINI, PL ;

ROSSETTI, R .

INORGANIC CHEMISTRY, 1991, 30 (10) :2282-2286

[4] HYDRIDE AND CARBONYL FLUCTIONALITY IN [HM10C(CO)24]- (M = RU, OS) [J].

BAILEY, PJ ;

GADE, LH ;

JOHNSON, BFG ;

LEWIS, J .

CHEMISCHE BERICHTE-RECUEIL, 1992, 125 (09) :2019-2023

[5] FAST ATOM BOMBARDMENT OF SOLIDS (FAB) - A NEW ION-SOURCE FOR MASS-SPECTROMETRY [J].

BARBER, M ;

BORDOLI, RS ;

SEDGWICK, RD ;

TYLER, AN .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (07) :325-327

[6] Solid state studies (X-ray and 1H-, 13C-NMR) on (NMe4)4-x[HxNi12(CO)21]•S (x = 1, S = Me2CO; x = 2, S = 2THF) [J].

Barkley, JV ;

Eguchi, T ;

Harding, RA ;

Heaton, BT ;

Longoni, G ;

Manzi, L ;

Nakayama, H ;

Miyagi, K ;

Smith, AK ;

Steiner, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 573 (1-2) :254-260

[7] SYNTHESIS AND STRUCTURAL-BONDING ANALYSIS OF (ETA-5-C5H4ME)4FE4(CO)6P8 AND (ETA-5-C5H4ME)4FE6(CO)13P8 - 2 UNPRECEDENTED TRANSITION-METAL COMPLEXES CONTAINING THE CAGE-LIKE P8 SUBUNIT OF HITTORF MONOCLINIC PHOSPHORUS ALLOTROPE [J].

BARR, ME ;

ADAMS, BR ;

WELLER, RR ;

DAHL, LF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (08) :3052-3060

[8] INFLUENCE OF HETERONUCLEARITY ON THE DIMERIZATION OF HFERU(CO)5(RC=C(H)C(H)=N-IPR)AND THE SYNTHESIS OF HETEROTETRANUCLEAR CHAIN COMPLEXES [J].

BEERS, OCP ;

ELSEVIER, CJ ;

SMEETS, WJJ ;

SPEK, AL .

ORGANOMETALLICS, 1993, 12 (08) :3199-3210

[9] H12Pd28(PtPMe3)(PtPPh3)(12)(CO)(27), a high-nuclearity Pd28Pt13 cluster containing 12 hydride atoms: A possible molecular hydrogen-storage model for palladium metal [J].

Bemis, JM ;

Dahl, LF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (19) :4545-4546

[10]

BENCINI A, 1999, INORGANIC ELECT STRU

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