The design and synthesis of β-trifluoromethylenol phosphates as potential insecticides

被引：10

作者：

Ding, YX ^{[1
]}

Huang, XG ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China

来源：

HETEROATOM CHEMISTRY | 2003年 / 14卷 / 04期

关键词：

NUCLEAR MAGNETIC-RESONANCE; STEREOSELECTIVE SYNTHESIS; ENOL PHOSPHATES; PHOSPHONATE; KETONES;

D O I：

10.1002/hc.10147

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new group of compounds, beta-trifluoromethylenol phosphates [(RO)(2)P(O) OCR= CHCF3], has been designed and prepared by several methods. Some of them showed good insecticidal activities. In the molecular structure, the designed leaving group can rearrange to a powerful electrophilic agent, beta,beta-difluorovinyl ketone, which would be a potential enzyme inhibitor. (C) 2003 Wiley Periodicals, Inc.

引用

页码：304 / 308

页数：5

共 16 条

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