High molecular weight functionalized poly(ethylene oxide)

被引:44
作者
Dimitrov, P
Hasan, E
Rangejov, S
Trzebicka, B
Dworak, A
Tsvetanov, CB [1 ]
机构
[1] Bulgarian Acad Sci, Inst Polymers, BU-1113 Sofia, Bulgaria
[2] Polish Acad Sci, Inst Coal Chem, PL-44102 Gliwice, Poland
关键词
ethylene oxide/glycidol and ethylene oxide/ethoxy ethyl glycidyl ether copolymers; associating properties; calcium amide-alkoxide;
D O I
10.1016/S0032-3861(02)00459-7
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Novel high molecular weight copolymers of ethylene oxide (EO) and glycidol or ethoxy ethyl glycidyl ether (EEGE) were obtained via suspension anionic coordination polymerization using calcium amide-alkoxide initiating system. H-1 and C-13 NMR spectroscopy were used for the structural characterization of the copolymers as well as for the determination of the molar content (up to 2 mot%) of the functional monomers incorporated into the PEO backbone. SEC measurements of the copolymers determined (M) over bar (n). in the range of (2-11) x 10(5) g/mol. Surprisingly low polydispersity values of average (M) over bar (w)/(M) over bar (n) = 1.5 were obtained for the EO/EEGE copolymers. The calcium amide-alkoxide initiated polymerization of EEGE resulted in high molecular weight polymers with relatively broad polydispersity values ((M) over bar (n) = (0.8-1.5) x 10(5) g/mol, (M) over bar (w)/(M) over bar (n) less than or equal to 4.2). EO/glycidol copolymers and polyglycidol were obtained after cleavage of the acetal protecting group of the EEGE units. Polymers with hydrophilic backbone bearing hydrophobic stearyl moieties were obtained after modification of EO/glycidol copolymers with stearic acid. Their associating properties in aqueous solution were studied. Increasing either temperature or polymer concentration induces aggregate formation. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:7171 / 7178
页数:8
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