Planar tetracoordinate carbon - A novel environment in a pentaruthenium cluster

被引：6

作者：

Adams, CJ

Bruce, MI

Skelton, BW

White, AH

机构：

[1] UNIV ADELAIDE,DEPT CHEM,ADELAIDE,SA 5005,AUSTRALIA

[2] UNIV WESTERN AUSTRALIA,DEPT CHEM,NEDLANDS,WA 6907,AUSTRALIA

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 08期

关键词：

D O I：

10.1039/cc9960000975

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Addition of Bu(t)NC to [Ru-5(mu-C-2(p-SMe)(2)(mu-PPh(2))(2)(CO)(11)] 1 results in expansion of the Ru-5 polygon and flattening of the C2Ru5 cluster so that in the product 2 one carbon atom acquires a planar tetracoordinate configuration; reversible loss of CO from 2 affords a CNBu(t) derivative of 1.

引用

页码：975 / 976

页数：2

共 16 条

[1] SYNTHESIS AND X-RAY STRUCTURES OF 2 COMPLEXES CONTAINING DICARBON (C2) ATTACHED TO RU5 CLUSTERS WITH UNUSUAL CORE GEOMETRIES
ADAMS, CJ
BRUCE, MI
SKELTON, BW
WHITE, AH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (01) : 26 - 29
[2] ALBRECHT M, 1993, SYNLETT, P441
[3] SYNTHESIS AND MOLECULAR-STRUCTURE OF MU4-CARBIDO-MU2-CARBONYL-DODECACARBONYLTETRAIRON, A NEUTRAL IRON BUTTERFLY CLUSTER BEARING AN EXPOSED CARBON-ATOM
BRADLEY, JS
ANSELL, GB
LEONOWICZ, ME
HILL, EW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (16) : 4968 - 4970
[4] STABILIZATION OF PLANAR TETRACOORDINATE CARBON
COLLINS, JB
DILL, JD
JEMMIS, ED
APELOIG, Y
SCHLEYER, PV
SEEGER, R
POPLE, JA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (18) : 5419 - 5427
[5] STRUCTURAL ASPECTS OF THE OSMIUM AND RUTHENIUM CLUSTERS [M3(CO)10(ALKYNE)] AND RELATED SUBSTITUTED COMPOUNDS
DEEMING, AJ
SENIOR, AM
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 439 (02) : 177 - 188
[6] DIEDERICH F, 1992, ANGEW CHEM, V104, P1123
[7] Erker G., 1992, COMMENT INORG CHEM, V13, P111, DOI DOI 10.1080/02603599208048461
[8] AN ABINITIO MO STUDY ON STABILIZING INTERACTIONS IN DINUCLEAR ZR/AL COMPLEXES WITH A PLANAR TETRACOORDINATE CARBON CENTER
GLEITER, R
HYLAKRYSPIN, I
NIU, SQ
ERKER, G
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (05): : 754 - 756
[9] GLEITER R, 1993, ANGEW CHEM, V105, P753
[10] HALET JF, 1995, COMMUNICATION

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