Planar tetracoordinate carbon - A novel environment in a pentaruthenium cluster

被引:6
作者
Adams, CJ
Bruce, MI
Skelton, BW
White, AH
机构
[1] UNIV ADELAIDE,DEPT CHEM,ADELAIDE,SA 5005,AUSTRALIA
[2] UNIV WESTERN AUSTRALIA,DEPT CHEM,NEDLANDS,WA 6907,AUSTRALIA
关键词
D O I
10.1039/cc9960000975
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Addition of Bu(t)NC to [Ru-5(mu-C-2(p-SMe)(2)(mu-PPh(2))(2)(CO)(11)] 1 results in expansion of the Ru-5 polygon and flattening of the C2Ru5 cluster so that in the product 2 one carbon atom acquires a planar tetracoordinate configuration; reversible loss of CO from 2 affords a CNBu(t) derivative of 1.
引用
收藏
页码:975 / 976
页数:2
相关论文
共 16 条
  • [11] HALL SR, 1989, XTAL USERS MANUAL VE
  • [12] PLANAR TETRACOORDINATE CARBON-ATOMS HIDDEN IN THE TETRAMERIC AGGREGATE OF (2,6-DIMETHOXYPHENYL)LITHIUM
    HARDER, S
    BOERSMA, J
    BRANDSMA, L
    VANHETEREN, A
    KANTERS, JA
    BAUER, W
    SCHLEYER, PV
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (23) : 7802 - 7806
  • [13] PLANAR TETRACOORDINATE CARBON
    HOFFMANN, R
    ALDER, RW
    WILCOX, CF
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (16) : 4992 - &
  • [14] Hoffmann R., 1971, Pure Appl.Chem, V28, P181, DOI [10.1351/pac197128020181, DOI 10.1351/PAC197128020181]
  • [15] A STABLE PALLADIUM(I) DIMER WITH ONE 14E PALLADIUM CENTER AND ITS REVERSIBLE-REACTION WITH CS2, AFFORDING A NEW COMPLEX WITH A PLANAR 4-COORDINATE CARBON
    LEONI, P
    PASQUALI, M
    PIERI, G
    ALBINATI, A
    PREGOSIN, PS
    RUEGGER, H
    [J]. ORGANOMETALLICS, 1995, 14 (07) : 3143 - 3145
  • [16] PLANAR TETRACOORDINATE CARBONS IN DIMETALLIC COMPLEXES - QUANTUM-CHEMICAL INVESTIGATIONS
    POUMBGA, CN
    BENARD, M
    HYLAKRYSPIN, I
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (18) : 8259 - 8265