Planar tetracoordinate carbon - A novel environment in a pentaruthenium cluster

被引：6

作者：

Adams, CJ

Bruce, MI

Skelton, BW

White, AH

机构：

[1] UNIV ADELAIDE,DEPT CHEM,ADELAIDE,SA 5005,AUSTRALIA

[2] UNIV WESTERN AUSTRALIA,DEPT CHEM,NEDLANDS,WA 6907,AUSTRALIA

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 08期

关键词：

D O I：

10.1039/cc9960000975

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Addition of Bu(t)NC to [Ru-5(mu-C-2(p-SMe)(2)(mu-PPh(2))(2)(CO)(11)] 1 results in expansion of the Ru-5 polygon and flattening of the C2Ru5 cluster so that in the product 2 one carbon atom acquires a planar tetracoordinate configuration; reversible loss of CO from 2 affords a CNBu(t) derivative of 1.

引用

页码：975 / 976

页数：2

共 16 条

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