The C1Σ+ state of KLi studied by polarisation labelling spectroscopy technique

被引:6
作者
Grochola, A
Kowalczyk, P
Jastrzebski, W
Crozet, P
Ross, AJ
机构
[1] Univ Warsaw, Inst Expt Phys, PL-00681 Warsaw, Poland
[2] Polish Acad Sci, Inst Phys, PL-02668 Warsaw, Poland
[3] Univ Lyon 1, Spectrometrie Ion & Mol Lab, F-69622 Villeurbanne, France
[4] CNRS, UMR 5579, F-69622 Villeurbanne, France
关键词
D O I
10.12693/APhysPolA.102.729
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The polarisation labelling spectroscopy method is applied to study the C(1)Sigma(+)<--X(1)Sigma(+) band system of the KLi molecule. Rotationally resolved polarisation spectra are observed in the spectral range of 17150-20350 cm(-1). A set of Dunham coefficients describes the C(1)Sigma(+) state to 95% of its potential well depth, and the potential curve is constructed by the Rydberg-Klein-Rees procedure. The molecular parameters deduced from this work are compared with theoretical calculations.
引用
收藏
页码:729 / 738
页数:10
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