Layered LixMn1-yNiyO2 intercalation electrodes

被引：58

作者：

Quine, TE ^{[1
]}

Duncan, MJ ^{[1
]}

Armstrong, AR ^{[1
]}

Robertson, AD ^{[1
]}

Bruce, PG ^{[1
]}

机构：

[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2000年 / 10卷 / 12期

关键词：

D O I：

10.1039/b007429m

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Synthesis of the layered lithium intercalation compound LixMn1 - yNiyO2, with the O3 (alpha -NaFeO2) structure is reported and it is shown to exhibit amongst the highest capacity to cycle lithium (charge) on intercalation/deintercalation (220 mA h g(-1) between potential limits of 2.4 to 4.8 V) of any such material and at a relatively high charge/discharge rate; the ion exchange conditions used in the synthesis have an important influence on the defect chemistry of the host structure and this in turn influences the performance of the compound as an electrode in rechargeable lithium batteries.

引用

页码：2838 / 2841

页数：4

共 28 条

[1] Synthesis of layered LiMnO2 as an electrode for rechargeable lithium batteries [J].

Armstrong, AR ;

Bruce, PG .

NATURE, 1996, 381 (6582) :499-500

[2]

Armstrong AR, 1998, CHEM COMMUN, P1833

[3] The layered intercalation compounds Li(Mn1-yCoy)O2:: Positive electrode materials for lithium-ion batteries [J].

Armstrong, AR ;

Robertson, AD ;

Gitzendanner, R ;

Bruce, PG .

JOURNAL OF SOLID STATE CHEMISTRY, 1999, 145 (02) :549-556

[4] Structural transformation on cycling layered Li(Mn1-yCoy)O2 cathode materials [J].

Armstrong, AR ;

Robertson, AD ;

Bruce, PG .

ELECTROCHIMICA ACTA, 1999, 45 (1-2) :285-294

[5] LIXNIO2, A PROMISING CATHODE FOR RECHARGEABLE LITHIUM BATTERIES [J].

BROUSSELY, M ;

PERTON, F ;

BIENSAN, P ;

BODET, JM ;

LABAT, J ;

LECERF, A ;

DELMAS, C ;

ROUGIER, A ;

PERES, JP .

JOURNAL OF POWER SOURCES, 1995, 54 (01) :109-114

[6] New intercalation compounds for lithium batteries:: layered LiMnO2 [J].

Bruce, PG ;

Armstrong, AR ;

Gitzendanner, RL .

JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (01) :193-198

[7] A new variety of LiMnO2 with a layered structure [J].

Capitaine, F ;

Gravereau, P ;

Delmas, C .

SOLID STATE IONICS, 1996, 89 (3-4) :197-202

[8] Identification of cathode materials for lithium batteries guided by first-principles calculations [J].

Ceder, G ;

Chiang, YM ;

Sadoway, DR ;

Aydinol, MK ;

Jang, YI ;

Huang, B .

NATURE, 1998, 392 (6677) :694-696

[9] THERMAL-STABILITY OF LIXCOO2, LIXNIO2 AND LAMBDA-MNO2 AND CONSEQUENCES FOR THE SAFETY OF LI-ION CELLS [J].

DAHN, JR ;

FULLER, EW ;

OBROVAC, M ;

VONSACKEN, U .

SOLID STATE IONICS, 1994, 69 (3-4) :265-270

[10] RECHARGEABLE LINIO2 CARBON CELLS [J].

DAHN, JR ;

VONSACKEN, U ;

JUZKOW, MW ;

ALJANABY, H .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (08) :2207-2211

← 1 2 3 →