Structural properties of liquid N,N-dimethylformamide

被引：10

作者：

Bushuev, YG ^{[1
]}

Zaichikov, AM ^{[1
]}

机构：

[1] Ivanovo State Acad Chem Technol, Ivanovo 153460, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1998年 / 47卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

organic solvents; N; N-dimethylformamide; structure of liquid; intermolecular interactions; computer simulation of liquids; Monte-Carlo method;

D O I：

10.1007/BF02495503

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Monte-Carlo simulation of liquid N,N-dimethylformamide was performed. The influence of electrostatic and van der Waals interactions on regularities of the mutual molecular arrangement was investigated. The spatial structure of liquid DMF is determined by the type of molecular packing and steric factors and is close to a random closely packed system of soft spheres. The electrostatic interactions only affect the mutual orientation of the molecules.

引用

页码：17 / 24

页数：8

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