Block copolymer libraries:: modular versatility of the macromolecular Lego® system

被引:27
作者
Lohmeijer, BGG
Wouters, D
Yin, ZH
Schubert, US
机构
[1] Eindhoven Univ Technol, Lab Macromol Chem & Nanosci, NL-5600 MB Eindhoven, Netherlands
[2] Dutch Polymer Inst, NL-5600 MB Eindhoven, Netherlands
关键词
D O I
10.1039/b411777h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis and characterization of a new 4 x 4 library of block copolymers based on polystyrene and poly(ethylene oxide) connected by an asymmetrical octahedral bis(terpyridine) ruthenium complex at the block junction are described, while initial studies on the thin film morphology of the components of the library are presented by the use of Atomic Force Microscopy, demonstrating the impact of a library approach to derive structure-property relationships.
引用
收藏
页码:2886 / 2887
页数:2
相关论文
共 18 条
  • [1] Melt morphology of polystyrene-poly(ethylene oxide) metallo-supramolecular diblock copolymer
    Al-Hussein, M
    Lohmeijer, BGG
    Schubert, US
    de Jeu, WH
    [J]. MACROMOLECULES, 2003, 36 (25) : 9281 - 9284
  • [2] BLOCK COPOLYMER THERMODYNAMICS - THEORY AND EXPERIMENT
    BATES, FS
    FREDRICKSON, GH
    [J]. ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1990, 41 (01) : 525 - 557
  • [3] Supramolecular polymers
    Brunsveld, L
    Folmer, BJB
    Meijer, EW
    Sijbesma, RP
    [J]. CHEMICAL REVIEWS, 2001, 101 (12) : 4071 - 4097
  • [4] Pathways to macroscale order in nanostructured block copolymers
    Chen, ZR
    Kornfield, JA
    Smith, SD
    Grothaus, JT
    Satkowski, MM
    [J]. SCIENCE, 1997, 277 (5330) : 1248 - 1253
  • [5] Microdomain patterns from directional eutectic solidification and epitaxy
    De Rosa, C
    Park, C
    Thomas, EL
    Lotz, B
    [J]. NATURE, 2000, 405 (6785) : 433 - 437
  • [6] Observed substrate topography-mediated lateral patterning of diblock copolymer films
    Fasolka, MJ
    Harris, DJ
    Mayes, AM
    Yoon, M
    Mochrie, SGJ
    [J]. PHYSICAL REVIEW LETTERS, 1997, 79 (16) : 3018 - 3021
  • [7] Lin ZQ, 2002, ADV MATER, V14, P1373, DOI 10.1002/1521-4095(20021002)14:19<1373::AID-ADMA1373>3.0.CO
  • [8] 2-F
  • [9] Expanding the supramolecular polymer LEGO system: Nitroxide-mediated living free-radical polymerization as a tool for mono- and telechelic polystyrenes
    Lohmeijer, BGG
    Schubert, US
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2004, 42 (16) : 4016 - 4027
  • [10] Water-soluble building blocks for terpyridine-containing supramolecular polymers: Synthesis, complexation, and pH stability studies of poly(ethylene oxide) moieties
    Lohmeijer, BGG
    Schubert, US
    [J]. MACROMOLECULAR CHEMISTRY AND PHYSICS, 2003, 204 (08) : 1072 - 1078