Formation of a [2+2]-heterotetranuclear macrocycle from reaction of a platina-homoditopic ligand with iron(II)

被引：23

作者：

Constable, EC ^{[1
]}

Housecroft, CE ^{[1
]}

Neuburger, M ^{[1
]}

Schaffner, S ^{[1
]}

Shardlow, EJ ^{[1
]}

机构：

[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland

来源：

DALTON TRANSACTIONS | 2005年 / 02期

关键词：

D O I：

10.1039/b416621c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of 4'-(2-propyn-1-oxy)-2,2':6',2"-terpyridine (HC= CCH(2)Oterpy) with trans-[PtI2(PEt3)(2)] regioselectively metallates the alkyne to give trans-[Pt(C=CCH(2)Oterpy)(2)(PEt3)(2)] which, when treated with Fe(II), gives a [2 + 2]-metallocycle.

引用

页码：234 / 235

页数：2

共 16 条

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