A conditioning-free magnesium chloride complex electrolyte for rechargeable magnesium batteries

被引：95

作者：

Ha, Jung Hoon ^{[1
,2
]}

Adams, Brian ^{[3
]}

Cho, Jae-Hyun ^{[1
]}

Duffort, Victor ^{[3
]}

Kim, Jong Hak ^{[2
]}

Chung, Kyung Yoon ^{[1
]}

Cho, Byung Won ^{[1
]}

Nazar, Linda F. ^{[3
]}

Oh, Si Hyoung ^{[1
]}

机构：

[1] Korea Inst Sci & Technol, Ctr Energy Convergence Res, Hwarang Ro 14 Gil 5, Seoul 136791, South Korea

[2] Yonsei Univ, Dept Chem & Biomol Engn, 262 Seongsanno, Seoul 120739, South Korea

[3] Univ Waterloo, Dept Chem, 200 Univ Ave W, Waterloo, ON N2L 3G1, Canada

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2016年 / 4卷 / 19期

关键词：

CRYSTAL-STRUCTURE; ELECTROCHEMISTRY; PERFORMANCE; INSERTION; CATHODES; PHASES; SALT; MG2+;

D O I：

10.1039/c6ta01684g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

The dissolution of Mg metal in AlCl3/THF using CrCl3 as a "promoter" yields a magnesium aluminum chloride complex electrolyte which shares many common features with MACC, but does not require an onerous conditioning process. This crucial advantage originates from the very high Mg to Al ratio in the new electrolyte, "MaCC", which promotes 100% coulombic efficiency for Mg in the first cycle.

引用

收藏

页码：7160 / 7164

页数：5

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