A Highly Stable Porphyrinic Zirconium Metal-Organic Framework with shp-a Topology

被引：353

作者：

Feng, Dawei ^{[1
]}

Gu, Zhi-Yuan ^{[1
]}

Chen, Ying-Pin ^{[1
]}

Park, Jihye ^{[1
]}

Wei, Zhangwen ^{[1
]}

Sun, Yujia ^{[1
]}

Bosch, Mathieu ^{[1
]}

Yuan, Shuai ^{[1
]}

Zhou, Hong-Cai ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 51期

关键词：

ADSORPTION;

D O I：

10.1021/ja510525s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Through a kinetically controlled synthetic process, we synthesized PCN-223, a new porphyrinic Zr-MOF constructed from the newly reported hexagonal prismatic 12-connected Zr-6 cluster through an unusual disordered arrangement, giving rise to the first example of the shp-a network in MOFs. With its extremely high connectivity, PCN-223 shows high stability in aqueous solutions with a wide range of pH. Cationic PCN-223(Fe) formed by postsynthetic treatment is an excellent recyclable heterogeneous catalyst for the hetero-Diels-Alder reaction.

引用

收藏

页码：17714 / 17717

页数：4

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