A Highly Stable Porphyrinic Zirconium Metal-Organic Framework with shp-a Topology

被引:353
作者
Feng, Dawei [1 ]
Gu, Zhi-Yuan [1 ]
Chen, Ying-Pin [1 ]
Park, Jihye [1 ]
Wei, Zhangwen [1 ]
Sun, Yujia [1 ]
Bosch, Mathieu [1 ]
Yuan, Shuai [1 ]
Zhou, Hong-Cai [1 ]
机构
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA
关键词
ADSORPTION;
D O I
10.1021/ja510525s
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Through a kinetically controlled synthetic process, we synthesized PCN-223, a new porphyrinic Zr-MOF constructed from the newly reported hexagonal prismatic 12-connected Zr-6 cluster through an unusual disordered arrangement, giving rise to the first example of the shp-a network in MOFs. With its extremely high connectivity, PCN-223 shows high stability in aqueous solutions with a wide range of pH. Cationic PCN-223(Fe) formed by postsynthetic treatment is an excellent recyclable heterogeneous catalyst for the hetero-Diels-Alder reaction.
引用
收藏
页码:17714 / 17717
页数:4
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