Removal of NOx and SO2 by CuO/γ-Al2O3 sorbent/catalyst in a fluidized-bed reactor

被引：60

作者：

Jeong, SM

Kim, SD ^{[1
]}

机构：

[1] Korea Adv Inst Sci & Technol, Dept Chem Engn, Taejon 305701, South Korea

[2] Korea Adv Inst Sci & Technol, Energy & Environm Res Ctr, Taejon 305701, South Korea

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2000年 / 39卷 / 06期

关键词：

D O I：

10.1021/ie990482r

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Selective reduction of NO and the simultaneous removal SO2/NO by CuO/gamma-Al2O3\ sorbent/catalyst were carried out in a fluidized-bed reactor. The optimum temperature ranges for NO reduction over the fresh and sulfated CuO/gamma-Al2O3 catalyst are found to be 250-300 and 300-450 degrees C, respectively. The NO removal efficiency with the sulfated catalyst is somewhat higher than that with the fresh catalyst. The amount of optimum Cu/S is found to be 1.5 in the simultaneous removal of SO2/NO. The optimum temperature range for the simultaneous removal of SO2/NO by CuO/gamma-Al2O3 sorbent/catalyst in the reactor is 350-400 degrees C based on the SO2 and NO removal efficiencies (> 90%) and N2O formation (< 10% of NO in feed).

引用

页码：1911 / 1916

页数：6

共 21 条

[11] Selective catalytic reduction of NO by NH3 over a bulk sulfated CuO/γ-Al2O3 catalyst [J].