Fluid inclusion studies combined with the isotope geochemistry of several generations of fracture calcite from the Olkiluoto research site, Finland, has been used to better understand the past thermal and fluid history in the crystalline rock environment. Typically, fracture mineral investigations use O and C isotopes from calcite and an estimate of the isotopic composition of the water that precipitated the calcite to perform delta(18)O geothermometry calculations to estimate past temperature conditions. By combining fluid inclusion information with calcite isotopes, one can directly measure the temperature at which the calcite formed and can better determine past fluid compositions. Isotopic, petrologic and fluid inclusion studies at the Olkiluoto research site in Finland were undertaken as part of an investigation within the Finnish nuclear waste disposal program. The study revealed that four fluids were recorded by fracture calcites. From petrologic evidence, the first fluid precipitated crystalline calcite at 151-225 degrees C with a delta(13)C signature of -21 to -13.9 parts per thousand PDB and a delta(18)O signature of 12.3-13.0 parts per thousand SMOW. These closed fracture fillings were found at depths greater than 500 m and were formed from a high temperature, low salinity, Na-Cl fluid of possible meteoric water altered by exchange with wallrock or dilute basinal origin. The next fluid precipitated crystalline calcite with clay at 92-210 degrees C with a delta(13)C signature of -2.6 to +3.8 parts per thousand PDB and a delta(18)O signature of 19.4-20.7 parts per thousand SMOW. These closed fracture fillings were found at depths less than 500 m and were formed from a moderate to high temperature, low to moderate salinity, Na-Cl fluid, likely of magmatic origin. The last group of calcites to form, record the presence of two distinct fluid types. The platy (a) calcite formed at 95-238 degrees C with a delta(13)C signature of -12.2 to -3.8 parts per thousand PDB and a delta(18)O signature of 14.9-19.6 parts per thousand SMOW, from a high temperature, low salinity, Na-Cl fluid of possible magmatic origin. The platy (b) calcite formed at 67-98 degrees C with a delta(13)C signature of -13.0 to -6.2 parts per thousand PDB and a delta(18)O signature of 15.1-20.1 parts per thousand SMOW, from a low temperature, high salinity, Ca-Na-Cl fluid of possible basinal brine origin. The two calcites are related through a mixing between the two end members. The source of the fluids for the platy grey (a) calcites could be the olivine diabase dykes and sills that cut through the site. The source of fluids for the platy (b) calcites could be the Jotnian arkosic sandstone formations in the northern part of the site. At the Olkiluoto site, delta(18)O geothermometry does not agree with fluid inclusion data. The original source of the water that forms the calcite has the largest effect on the isotopic signature of the calcites formed. Large isotopic shifts are seen in any water by mineral precipitation during cooling under rock-water equilibrium fractionation conditions. Different calcite isotopic signatures are produced depending on whether cooling occurred in an open or closed system. Water-rock interaction, at varying W/R ratios, between a water and a host rock can explain the isotopic shifts in many of the calcites observed. In some cases it is possible to shift the delta(18)O of the water by +11.5 parts per thousand (SMOW) using a realistic water-rock ratio. This process still does not explain some of the very positive delta(18)O values calculated using fluid inclusion data. Several other processes, such as low temperature recrystallization, boiling, kinetic effects and dissolution of calcite front fluid inclusion walls can affect isotopic signatures to varying degrees. The discrepancy between fluid inclusion data and delta(18)O geothermometry at the Olkiluoto site was most likely due to poor constraint on the original source of the water. (C) 2000 Elsevier Science Ltd. All rights reserved.
