Structure and kinetics of novel cyclophane inclusion compounds

被引：6

作者：

Apel, S

Czugler, M

Griffith, VJ

Nassimbeni, LR

Weber, E

机构：

[1] UNIV CAPE TOWN, DEPT CHEM, ZA-7700 RONDEBOSCH, SOUTH AFRICA

[2] TECH UNIV BERGAKAD FREIBERG, INST ORGAN CHEM, D-09596 FREIBERG, GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1997年 / 10期

关键词：

D O I：

10.1039/a702583a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel cyclophane host compound, 3, featuring a macrocyclic structure-with two hydroquinone dimethyl ether and two 1,1-diphenylcyclohexane construction elements assembled via benzylic ether linkages has been synthesised and its inclusion compounds with toluene, 4, and cyclohexanone, 5, have been characterised by thermal analysis and X-ray crystallography, The conformation of the cyclophane is markedly different in the two inclusion compounds. The kinetics of desolvation of 5 are deceleratory and yield an activation energy of 182 kJ mol(-1).

引用

页码：1949 / 1953

页数：5

共 24 条

[11] STRUCTURE OF HOST-GUEST COMPLEXES OF 1',1''-DIMETHYL-DISPIRO[1,6,20,25-TETRAOXA[6.1.6.1]PARACYCLOPHANE-13,4'-32,4''-BISPIPERIDINE] WITH BENZENE AND PARA-XYLENE [J].