SnSe Nanocrystals: Synthesis, Structure, Optical Properties, and Surface Chemistry

被引：269

作者：

Baumgardner, William J. ^{[1
]}

Choi, Joshua J. ^{[2
]}

Lim, Yee-Fun ^{[2
]}

Hanrath, Tobias ^{[3
]}

机构：

[1] Cornell Univ, Dept Chem & Chem Biol, Ithaca, NY 14853 USA

[2] Cornell Univ, Sch Appl & Engn Phys, Ithaca, NY 14853 USA

[3] Cornell Univ, Sch Chem & Biomol Engn, Ithaca, NY 14853 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 28期

关键词：

COLLOIDAL QUANTUM DOTS; ELECTRONIC-STRUCTURE; SHORT-CHAIN; PBSE; MONOCHALCOGENIDES; GENERATION; EFFICIENT; FILMS; SNTE;

D O I：

10.1021/ja1013745

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The colloidal synthesis of SnSe nanoparticles is accomplished through the injection of bis[bis(trimethylsilyl)amino]tin(II) into hot trioctylphosphine:selenium in the presence of oleylamine. Through the manipulation of reaction temperature particles are grown with the average diameter reliably tuned to 4-10 nm. Quantum confinement is examined by establishing a relationship between particle size and band gap while the in depth growth dynamics are illuminated through UV-vis-NIR spectroscopy. Surface chemistry effects are explored, including the demonstration of useful ligand exchanges and the development of routes toward anisotropic particle growth. Finally, transient current-voltage properties of SnSe nanocrystal films in the dark and light are examined.

引用

页码：9519 / 9521

页数：3

共 26 条

[1] The peculiar electronic structure of PbSe quantum dots
An, J. M.
Franceschetti, A.
Dudiy, S. V.
Zunger, Alex
[J]. NANO LETTERS, 2006, 6 (12) : 2728 - 2735
[2] XRD and 119Sn Mossbauer spectroscopy characterization of SnSe obtained from a simple chemical route
Bernardes-Silva, AC
Mesquita, AF
Neto, ED
Porto, AO
Ardisson, JD
de Lima, GM
Lameiras, FS
[J]. MATERIALS RESEARCH BULLETIN, 2005, 40 (09) : 1497 - 1505
[3] NEUTRON-DIFFRACTION STUDY OF THE STRUCTURAL PHASE-TRANSITION IN SNS AND SNSE
CHATTOPADHYAY, T
PANNETIER, J
VONSCHNERING, HG
[J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1986, 47 (09) : 879 - 885
[4] PbSe Nanocrystal Excitonic Solar Cells
Choi, Joshua J.
Lim, Yee-Fun
Santiago-Berrios, Mitk'El B.
Oh, Matthew
Hyun, Byung-Ryool
Sung, Liangfeng
Bartnik, Adam C.
Goedhart, Augusta
Malliaras, George G.
Abruna, Hector D.
Wise, Frank W.
Hanrath, Tobias
[J]. NANO LETTERS, 2009, 9 (11) : 3749 - 3755
[5] The electronic structure of semiconductor nanocrystals
Efros, AL
Rosen, M
[J]. ANNUAL REVIEW OF MATERIALS SCIENCE, 2000, 30 : 475 - 521
[6] Highly efficient multiple exciton generation in colloidal PbSe and PbS quantum dots
Ellingson, RJ
Beard, MC
Johnson, JC
Yu, PR
Micic, OI
Nozik, AJ
Shabaev, A
Efros, AL
[J]. NANO LETTERS, 2005, 5 (05) : 865 - 871
[7] Solution-Phase Synthesis of SnSe Nanocrystals for Use in Solar Cells
Franzman, Matthew A.
Schlenker, Cody W.
Thompson, Mark E.
Brutchey, Richard L.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (12) : 4060 - +
[8] Size and Shape Control of Colloidally Synthesized IV-VI Nanoparticulate Tin(II) Sulfide
Hickey, Stephen G.
Waurisch, Christian
Rellinghaus, Bernd
Eychmueller, Alexander
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (45) : 14978 - +
[9] A Novel Example of Molecular Hydrogen Generation from Formic Acid at Visible-Light-Responsive Photocatalyst
Kakuta, Seiji
Abe, Toshiyuki
[J]. ACS APPLIED MATERIALS & INTERFACES, 2009, 1 (12) : 2707 - 2710
[10] Efficient, stable infrared photovoltaics based on solution-cast colloidal quantum dots
Koleilat, Ghada I.
Levina, Larissa
Shukla, Harnik
Myrskog, Stefan H.
Hinds, Sean
Pattantyus-Abraham, Andras G.
Sargent, Edward H.
[J]. ACS NANO, 2008, 2 (05) : 833 - 840

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