The binding energy of Ar to p-difluorobenzene-Ar.: How large are three-body effects in p-difluorobenzene-Ar2?

被引：7

作者：

Bellm, SM ^{[1
]}

Lawrance, WD ^{[1
]}

机构：

[1] Flinders Univ S Australia, Sch Chem Phys & Earth Sci, Adelaide, SA 5001, Australia

来源：

CHEMICAL PHYSICS LETTERS | 2003年 / 368卷 / 5-6期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1016/S0009-2614(02)01899-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The technique of velocity map imaging has been used to determine the dissociation energy for the process p-difluorobenzene-Ar-2 --> p-difluorobenzene-Ar + Ar. The aim of the experiment was to obtain a value for comparison with the dissociation energy for the process p-difluorobenzene-Ar --> p-difluorobenzene + Ar in order to ascertain the extent of three-body effects. We find that the dissociation energy for the loss of an Ar atom from p-difluorobenzene-Ar-2 is 339 +/- 3 cm(-1), which is the same within experimental uncertainty as that for the loss of Ar from p-difluorobenzene-Ar (337 +/- 4 cm(-1)). We conclude that the presence of the first Ar affects the binding energy of the second by similar to2% or less. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：542 / 546

页数：5

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