Real-time probing of vectorial properties of ultra-fast photodissociations in liquids

被引：14

作者：

Bürsing H. ^{[1
]}

Lindner J. ^{[1
]}

Hess S. ^{[1
]}

Vöhringer P. ^{[1
]}

机构：

[1] Max-Planck-Inst. Biophysical C., Dynamics Group, 37077 Göttingen

来源：

Applied Physics B | 2000年 / 71卷 / 3期

关键词：

PACS: 78.47+p; 82.40.Js; 82.50.Fv;

D O I：

10.1007/s003400000344

中图分类号：

学科分类号：

摘要：

Polarization-resolved femtosecond experiments are shown to yield valuable insight into transition-state dynamics associated with ultra-fast photodissociation reactions of triatomic species in liquid solution. After the fundamental act of bond fission is completed, such experiments reveal rotational dynamics of the fragments, which can be used to extract information regarding fragment rotational excitation in the asymptotic limit of the reaction.

引用

页码：411 / 417

页数：6

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