Constructed wetlands for the treatment of organic pollutants

Background. Constructed wetlands (wetland treatment systems) are wetlands designed to improve water quality. They use the same processes that occur in natural wetlands but have the flexibility of being constructed. As in natural wetlands vegetation, soil and hydrology are the major components. Different soil types and plant species are used in constructed wetlands. Regarding hydrology surface flow and subsurface flow constructed wetlands are the main types. Subsurface flow constructed wetlands are further subdivided into horizontal or vertical flow. Many constructed wetlands deal with domestic wastewater where BOD and COD (Biochemical and Chemical Oxygen Demand respectively) are used as a sum parameter for organic matter. However, also special organic compounds can be removed. Objective. The objectives are to summarise the state-of-the-art on constructed wetlands for treatment of specific organic compounds, to the present the lack of knowledge, and to derive future research needs. Methods. Case studies in combination with a literature review are used to summarise the available knowledge on removal processes for specific organic compounds. Results and Discussion. Case studies are presented for the treatment of wastewaters contaminated with aromatic organic compounds, and sulphonated anthraquinones, olive mill wastewater, landfill leachare, and groundwater contaminated with hydrocarbons, cyanides, chlorinated volatile organics, and explosives. In general the removal efficiency for organic contaminants is high in all presented studies. Conclusion. Constructed wetlands are an effective and low cost way to treat water polluted with organic compounds. There is a lack of knowledge on the detailed removal pathways for most of the contaminants. Removal rates as well as optimal plant species are substance-specific, and also typically not available. If a constructed wetland provides different environmental conditions and uses different plant species the treatment efficiency can be improved. Recommendations and Outlook. There is a great need to lighten the black box 'constructed wetland' to obtain performance data for both microbial activity and the contribution of the plants to the overall removal process. Also genetic modified plants should be considered to enhance the treatment performance of constructed wetlands for specific compounds.