A voltammetric electronic tongue made of modified epoxy-graphite electrodes for the qualitative analysis of wine

被引:4
作者
Juan Manuel Gutiérrez
Laura Moreno-Barón
Maria Isabel Pividori
Salvador Alegret
Manel del Valle
机构
[1] Universitat Autònoma de Barcelona,Sensors and Biosensors Group, Department of Chemistry
来源
Microchimica Acta | 2010年 / 169卷
关键词
Voltammetric sensor; Electronic tongue; Wine analysis; Principal component analysis; Artificial neural networks;
D O I
暂无
中图分类号
学科分类号
摘要
First results are presented of a new voltammetric electronic tongue which employs modified epoxy-graphite electrodes. This analytical tool has been applied to qualitative wine analysis, performing the classification of wine varieties, as well as recognition of the oxygenation effect. In the same way, studies related to the detection of some defects in wine production were also assessed, such as its vinegary taste in open-air contact or the use of excess sulphite preservative. The electronic tongue was formed by five voltammetric electrodes, four of them being bulk-modified with different substances: copper and platinum nanoparticles on one side, and polyaniline and polypyrrole powder on the other. The responses were preprocessed employing Principal Component Analysis (PCA) to visualize and identify distinct episodes. The resulting PCA scores were modelled with an artificial neural network that accomplishes final prediction with the qualitative classification of wines and/or detection of defects.
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页码:261 / 268
页数:7
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共 191 条
[11]  
Ivarsson P(2000)Application of a combined artificial olfaction and taste system to the quantification of relevant compounds in red wine Sens Actuators B 69 342-undefined
[12]  
Krantz-Rülcker C(2004)Wine classification by taste sensors made from ultra-thin films and using neural networks Sens Actuators B 98 77-undefined
[13]  
Winquist F(2004)Electrochemical Sensor array made from bisphthalocyanine modified carbon paste electrodes for discrimination of red wines Electrochim Acta 49 5177-undefined
[14]  
Lundström I(2007)Using an e-tongue based on voltammetric electrodes to discriminate among red wines aged in oak barrels or aged using alternative methods: Correlation between electrochemical signals and analytical parameters Electrochim Acta 52 2588-undefined
[15]  
Legin A(2008)Electronic tongue based on voltammetric electrodes modified with materials showing complementary electroactive properties Applications, Microchim Acta 163 23-undefined
[16]  
Rudnitskaya A(2007)Development of an electronic tongue based on a PEDOT-modified voltammetric sensor Anal Bioanal Chem 387 2101-undefined
[17]  
Seleznev B(2008)Amperometric sensors based on poly(3, 4-ethylenedioxythiophene)-modified electrodes: discrimination of white wines Anal Chim Acta 614 213-undefined
[18]  
Vlasov Y(2005)Classification of chinese yellow wines by chemometric analysis of cyclic voltammogram of copper electrodes Sensors 5 529-undefined
[19]  
Bleibaum RN(2006)Electronic tongue based on chemically modified electrodes and voltammetry for the detection of adulterations in wines Sens Actuators B 118 448-undefined
[20]  
Stone H(2007)Classification of multiple defect concentrations in white wine by platinum microelectrode voltammetry Sens Actuators B 125 462-undefined