LOW PRESSURE OLIGOMERIZATION OF MONO-OLEFINS WITH SOLUBLE NICKEL-ALUMINUM BIMETAL CATALYSTS .2. REACTION KINETICS OF PROPENE DIMERIZATION

被引：28

作者：

ONSAGER, OT

WANG, H

BLINDHEI.U

机构：

[1] Zentralinstitut für Industrielle Forschung, Oslo, Blindern

来源：

HELVETICA CHIMICA ACTA | 1969年 / 52卷 / 01期

关键词：

D O I：

10.1002/hlca.19690520120

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetics of the dimerization of propene in organic solvents under the influence of a homogeneous catalyst containing π‐tetramethylcyclobutadiene‐nickel dichloride and a prereacted mixture of ethylaluminiumdichloride and tri‐n‐butylphosphin are reported. The primary reaction products are: 2‐methyl‐1‐pentene, 4‐methyl‐2‐pentene (cis/trans), 2,3‐dimethyl‐1‐butene and 2‐Hexene (cis/trans) The results are in accordance with a coordinative mechanism on nickel. New results on the reaction between ethylaluminiumdichloride and O, N and P containing electrondonors are also discussed. Copyright © 1969 Verlag GmbH & Co. KGaA, Weinheim

引用

页码：196 / &

共 19 条

[11] ELECTRON DEFICIENT MOLECULES .2. ALUMINUM ALKYLS [J].