OXIDATIVE ADDITION OF PHOSPHORUS YLIDES TO RU3(CO)12

被引：16

作者：

BOHLE, DS

HEINEKE, D

TIRIPICCHIO, A

CAMELLINI, MT

VAHRENKAMP, H

机构：

[1] UNIV FREIBURG,INST ANORGAN & ANALYT CHEM,ALBERTSTR 21,W-7800 FREIBURG,GERMANY

[2] UNIV PARMA,CNR,CTR STUDIO STRUTT DIFFRATOMET,IST CHIM GEN & INORGAN,I-43100 PARMA,ITALY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 08期

关键词：

D O I：

10.1002/anie.199008961

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Ru3C‐cluster 1 with a C‐bonded phosphane ligand is the final product of the reaction of Ph3PCH2 with Ru3(CO)12. This cluster could be structurally characterized, as also could a phosphonio enolate isolated as intermediate. The formation of 1 completes the use of all methane H‐atoms in the sequence CH4 → CH3I → CH2 = PPh3 → 1. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

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页码：896 / 898

页数：3

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