CHEMOSELECTIVE HYDROGENATION OF THE DOUBLE-BOND OF VINYL EPOXIDES WITH HOMOGENEOUS PALLADIUM AND IRIDIUM CATALYSTS

被引：13

作者：

CHO, IS ^{[1
]}

LEE, B ^{[1
]}

ALPER, H ^{[1
]}

机构：

[1] UNIV OTTAWA,DEPT CHEM,OTTAWA,ON K1N 6N5,CANADA

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 34期

关键词：

D O I：

10.1016/0040-4039(95)01188-N

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The selective hydrogenation of the double bond of vinyl epoxides is catalyzed by either the species generated by treatment of the binuclear palladium complex, [(Bu(2)(t)PH)PdPBu(2)(t)](2) with oxygen, or by the cationic iridium(I) complex, [Ir(CoD)(PPh(3))(PhCN)]BF4, to produce the corresponding saturated epoxides at room temperature, and with good selectivity.

引用

页码：6009 / 6012

页数：4

共 19 条

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