SYNTHESIS AND MASS-SPECTRAL ANALYSIS OF C-60-DIHALOCARBENE ADDUCTS

被引：14

作者：

ISHIDA, T ^{[1
]}

FURUDATE, T ^{[1
]}

NOGAMI, T ^{[1
]}

KUBOTA, M ^{[1
]}

HIRANO, T ^{[1
]}

OHASHI, M ^{[1
]}

机构：

[1] UNIV ELECTROCOMMUN,DEPT APPL PHYS & CHEM,CHOFU,TOKYO 182,JAPAN

来源：

FULLERENE SCIENCE AND TECHNOLOGY | 1995年 / 3卷 / 04期

关键词：

D O I：

10.1080/153638X9508543794

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The monoadducts of C-60 with dibromo-, bromochloro-, and diiodocarbenes were synthesized and characterized. The mass spectra (MS) of C(60)CXY (X,Y = Cl, CI; Br, Br; and Br, Cl) were measured by the FAB, ESI, MALDI, and LD methods. The LDMS revealed that oligomerization reaction occurred to exhibit signals ascribable to C-2n (2n = 122 - 132 and 184 - 196).

引用

页码：399 / 409

页数：11

共 12 条

[1]

HILLENKAMP F, 1991, ANAL CHEM, V63, pA1193

[2] OBSERVATION OF THE FULLERENE ANIONS C-60(-) AND C-70(-) BY ELECTROSPRAY IONIZATION [J].

HIRAOKA, K ;

KUDAKA, I ;

FUJIMAKI, S ;

SHINOHARA, H .

RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 1992, 6 (04) :254-256

[3]

HIRSCH A, 1993, ANGEW CHEM INT EDIT, V32, P1138, DOI 10.1002/anie.199311381

[4]

ISHIDA T, 1994, SULLERENE SCI TECHN, V2, P165

[5] C-60 - BUCKMINSTERFULLERENE [J].

KROTO, HW ;

HEATH, JR ;

OBRIEN, SC ;

CURL, RF ;

SMALLEY, RE .

NATURE, 1985, 318 (6042) :162-163

[6]

LIU MTH, IN PRESS ORG MASS SP

[7] A LASER-SPECIFIC C-C BOND FORMATION OF BICHROMOPHORIC COMPOUNDS [J].

OUCHI, A ;

YABE, A .

TETRAHEDRON LETTERS, 1990, 31 (12) :1727-1730

[8] A REMARKABLE WAVELENGTH DEPENDENCE ON THE LASER-INDUCED 2-PHOTON C-C BOND FORMATION [J].

OUCHI, A ;

YABE, A .

TETRAHEDRON LETTERS, 1992, 33 (37) :5359-5362

[9] C61CL2 - SYNTHESIS AND CHARACTERIZATION OF DICHLOROCARBENE ADDUCTS OF C-60 [J].

TSUDA, M ;

ISHIDA, T ;

NOGAMI, T ;

KURONO, S ;

OHASHI, M .

TETRAHEDRON LETTERS, 1993, 34 (43) :6911-6912

[10] PROGRESS IN THE DESIGN OF SELECTORS FOR BUCKMINSTERFULLERENE [J].

WELCH, CJ ;

PIRKLE, WH .

JOURNAL OF CHROMATOGRAPHY, 1992, 609 (1-2) :89-101

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