OBSERVATION OF THE FULLERENE ANIONS C-60(-) AND C-70(-) BY ELECTROSPRAY IONIZATION

被引：43

作者：

HIRAOKA, K ^{[1
]}

KUDAKA, I ^{[1
]}

FUJIMAKI, S ^{[1
]}

SHINOHARA, H ^{[1
]}

机构：

[1] MIE UNIV,DEPT CHEM MAT,TSU,MIE 514,JAPAN

来源：

RAPID COMMUNICATIONS IN MASS SPECTROMETRY | 1992年 / 6卷 / 04期

关键词：

D O I：

10.1002/rcm.1290060406

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Mass spectrometric investigation on the fullerenes C60 and C70 was performed using electrospray ionization. C60-, C60O2-, C70-, and C70O2- ions were detected by reducing C60 and C70 using NaK amalgam in benzene + dimethoxyethane solvent. C70- was found to be much more reactive than C60- in solution.

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页码：254 / 256

页数：3

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