NONSUPERCONDUCTING PHASE OF BIS(3,4-3',4'-ETHYLENEDITHIO)-2,2',5,5'-TETRATHIAFULVALENE-TETRAKIS(TRIFLUOROMETHYL)ARGENTATE(III) (2/1), (BEDT-TTF)(2)[AG(CF3)(4)]

被引：8

作者：

GEISER, U

SCHLUETER, JA

DUDEK, JD

WILLIAMS, JM

NAUMANN, D

ROY, T

机构：

[1] ARGONNE NATL LAB,DIV SCI MAT,ARGONNE,IL 60439

[2] UNIV COLOGNE,INST ANORGAN CHEM,D-50939 COLOGNE,GERMANY

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷 / pt 9期

关键词：

D O I：

10.1107/S0108270195003064

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The semiconductive phase in the system BEDT-TTF:[Ag(CF3)(4)](-), where BEDT-TTF is 3,4;3',4'-bis(ethylenedithio)-2,2',5,5'-tetrathiafulvalene {alternative IUPAC name: 5,5',6,6'-tetrahydro-2,2'-bi(1,3-dithiolo-[4,5-b][1,4]dithiinylidene), C10H8S8} contains theta-packing motif type layers of the electron-donor molecules. The anion has a planar AgC4 core and its trifluoromethyl groups are crystallographically ordered.

引用

页码：1779 / 1782

页数：4

共 9 条

[1] VAN DER WAALS VOLUMES + RADII [J].

BONDI, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+

[2]

GEISER U, 1995, IN PRESS ACTA CRYS B, V51

[3] CRYSTAL AND ELECTRONIC-STRUCTURES OF LAYERED MOLECULAR SUPERCONDUCTOR, THETA-(BEDT-TTF)2(I3)1-X(AUI2)X [J].

KOBAYASHI, H ;

KATO, R ;

KOBAYASHI, A ;

NISHIO, Y ;

KAJITA, K ;

SASAKI, W .

CHEMISTRY LETTERS, 1986, (05) :833-836

[4] INCLUSION OF SECONDARY EXTINCTION IN LEAST-SQUARES CALCULATIONS [J].

LARSON, AC .

ACTA CRYSTALLOGRAPHICA, 1967, 23 :664-&

[5] A NEW 9-K SUPERCONDUCTING ORGANIC SALT COMPOSED OF THE BIS(ETHYLENEDITHIO) TETRATHIAFULVALENE (ET) ELECTRON-DONOR MOLECULE AND THE TETRAKIS (TRIFLUOROMETHYL) CUPRATE (III) ANION, [CU(CF3)4]- [J].

SCHLUETER, JA ;

CARLSON, KD ;

WILLIAMS, JM ;

GEISER, U ;

WANG, HH ;

WELP, U ;

KWOK, WK ;

FENDRICH, JA ;

DUDEK, JD ;

ACHENBACH, CA ;

KEANE, PM ;

KOMOSA, AS ;

NAUMANN, D ;

ROY, T ;

SCHIRBER, JE ;

BAYLESS, WR .

PHYSICA C, 1994, 230 (3-4) :378-384

[6] THE FIRST ORGANIC CATION-RADICAL SALT SUPERCONDUCTOR (T-C=4K) WITH AN ORGANOMETALLIC ANION - SUPERCONDUCTIVITY, SYNTHESIS AND STRUCTURE OF K-L-(BEDT-TTF)(2)CU(CF3)(4)CENTER-DOT-TCE [J].

SCHLUETER, JA ;

GEISER, U ;

WILLIAMS, JM ;

WANG, HH ;

KWOK, WK ;

FENDRICH, JA ;

CARLSON, KD ;

ACHENBACH, CA ;

DUDEK, JD ;

NAUMANN, D ;

ROY, T ;

SCHIRBER, JE ;

BAYLESS, WR .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (13) :1599-1600

[7] SUPERCONDUCTIVITY UP TO 11.1-K IN 3 SOLVATED SALTS COMPOSED OF [AG(CF3)(4)](-) AND THE ORGANIC ELECTRON-DONOR MOLECULE BIS(ETHYLENEDITHIO)TETRATHIAFULVALENE (ET) [J].

SCHLUETER, JA ;

CARLSON, KD ;

GEISER, U ;

WANG, HH ;

WILLIAMS, JM ;

KWOK, WK ;

FENDRICH, JA ;

WELP, U ;

KEANE, PM ;

DUDEK, JD ;

KOMOSA, AS ;

NAUMANN, D ;

ROY, T ;

SCHIRBER, JE ;

BAYLESS, WR ;

DODRILL, B .

PHYSICA C, 1994, 233 (3-4) :379-386

[8]

STROUSE CE, 1985, UCLA CRYSTALLOGRAPHI

[9]

Williams JM, 1992, ORGANIC SUPERCONDUCT

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