PHOTOELECTRON EMISSION STUDY OF IRON(II) AND COBALT(II) COMPLEXES IN AQUEOUS-SOLUTION - REORGANIZATION ENERGIES

被引：18

作者：

WATANABE, I ^{[1
]}

ONO, K ^{[1
]}

IKEDA, S ^{[1
]}

机构：

[1] RYUKOKU UNIV, FAC SCI & TECHNOL, OTSU, SHIGA 52021, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 02期

关键词：

D O I：

10.1246/bcsj.64.352

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photoelectron emission threshold energies of Fe(II) and Co(II) complexes in aqueous solutions have been determined. The values could be successfully used for obtaining the reorganization energies in the one-electron oxidation reaction of these complexes. The obtained reorganization energies were found to be correlated with the rate constants of the electron-self-exchange reactions of Fe(II)/Fe(III) and Co(II)/Co(III).

引用

页码：352 / 357

页数：6

共 21 条

[1] THE ROLE OF INNER-SPHERE CONFIGURATION CHANGES IN ELECTRON-EXCHANGE REACTIONS OF METAL-COMPLEXES [J].

BRUNSCHWIG, BS ;

CREUTZ, C ;

MACARTNEY, DH ;

SHAM, TK ;

SUTIN, N .

FARADAY DISCUSSIONS, 1982, 74 :113-127

[2] CORRELATION BETWEEN THERMAL ELECTRON-TRANSFER IN SOLUTION AND PHOTO-ELECTRON EMISSION [J].

DELAHAY, P .

CHEMICAL PHYSICS LETTERS, 1982, 87 (06) :607-611

[3] PHOTOELECTRON EMISSION-SPECTROSCOPY OF INORGANIC CATIONS IN AQUEOUS-SOLUTION [J].

DELAHAY, P ;

VONBURG, K ;

DZIEDZIC, A .

CHEMICAL PHYSICS LETTERS, 1981, 79 (01) :157-161

[4]

Delahay P., 1983, Chemical Physics Letters, V96, P613, DOI 10.1016/0009-2614(83)80059-1

[5] PHOTO-ELECTRON EMISSION-SPECTROSCOPY OF AQUEOUS-SOLUTIONS [J].

DELAHAY, P .

ACCOUNTS OF CHEMICAL RESEARCH, 1982, 15 (02) :40-45

[6] ANOMALOUS REORGANIZATION FREE-ENERGIES IN OPTICAL ELECTRON-TRANSFER IN SOLUTION [J].

DELAHAY, P .

CHEMICAL PHYSICS LETTERS, 1982, 90 (06) :425-429

[7] INNER-SPHERE REORGANIZATION IN OPTICAL ELECTRON-TRANSFER [J].

DELAHAY, P ;

DZIEDZIC, A .

JOURNAL OF CHEMICAL PHYSICS, 1984, 80 (11) :5793-5798

[8]

DELARMINAT MA, 1984, PROSTATE, V5, P123

[9]

DHAN SUM, 1983, CHEM PHYS LETT, V99, P83

[10] EXAMINATION OF THE INTRINSIC BARRIER TO ELECTRON-TRANSFER IN HEXAAQUOCOBALT(III) - EVIDENCE FOR VERY SLOW OUTER-SPHERE SELF-EXCHANGE RESULTING FROM CONTRIBUTIONS OF FRANCK-CONDON AND ELECTRONIC TERMS [J].

ENDICOTT, JF ;

DURHAM, B ;

KUMAR, K .

INORGANIC CHEMISTRY, 1982, 21 (06) :2437-2444

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