PHOTOELECTRON EMISSION STUDY OF IRON(II) AND COBALT(II) COMPLEXES IN AQUEOUS-SOLUTION - REORGANIZATION ENERGIES

被引：18

作者：

WATANABE, I ^{[1
]}

ONO, K ^{[1
]}

IKEDA, S ^{[1
]}

机构：

[1] RYUKOKU UNIV, FAC SCI & TECHNOL, OTSU, SHIGA 52021, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 02期

关键词：

D O I：

10.1246/bcsj.64.352

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photoelectron emission threshold energies of Fe(II) and Co(II) complexes in aqueous solutions have been determined. The values could be successfully used for obtaining the reorganization energies in the one-electron oxidation reaction of these complexes. The obtained reorganization energies were found to be correlated with the rate constants of the electron-self-exchange reactions of Fe(II)/Fe(III) and Co(II)/Co(III).

引用

页码：352 / 357

页数：6