NEW CHIRAL ANISOTROPIC REAGENTS, NMR TOOLS TO ELUCIDATE THE ABSOLUTE-CONFIGURATIONS OF LONG-CHAIN ORGANIC-COMPOUNDS

被引：105

作者：

KUSUMI, T

TAKAHASHI, H

XU, P

FUKUSHIMA, T

ASAKAWA, Y

HASHIMOTO, T

KAN, Y

INOUYE, Y

机构：

[1] BEIJING MED UNIV,SCH PHARMACEUT SCI,BEIJING 100083,PEOPLES R CHINA

[2] JAPAN TOBACCO INC,YOKOHAMA CTR,APPL PLANT RES LAB,YOKOHAMA 227,JAPAN

[3] TOKUSHIMA BUNRI UNIV,FAC PHARMACEUT SCI,TOKUSHIMA 770,JAPAN

[4] UNIV TSUKUBA,DEPT CHEM,TSUKUBA,IBARAKI 305,JAPAN

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 25期

关键词：

D O I：

10.1016/S0040-4039(00)73366-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Modified Mosher's method has been extended by use of 9-anthranylmethoxyacetic acid (9ATMA) and 2-naphdiylmethoxynaphthylacetic acid (2NMA) instead of MTPA of the conventional method. Anisotropic effects of these reagents are much greater than that of MTPA, and die reagents have been shown to be useful especially to determine the absolute configurations of the secondary alcohols involved in long-chain compounds.

引用

页码：4397 / 4400

页数：4

共 11 条

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