HIGHLY ENANTIOSELECTIVE AND DIASTEREOSELECTIVE REDUCTION OF SULFUR-FUNCTIONALIZED CYCLIC-KETONES WITH BAKERS-YEAST

被引:27
作者
FUJISAWA, T
YAMANAKA, K
MOBELE, BI
SHIMIZU, M
机构
[1] Department of Chemistry for Materials, Mie University, Tsu, Mie
关键词
D O I
10.1016/S0040-4039(00)92638-8
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Bakers' yeast reduction of 2-phenylthiocyclopentanone, 2-phenylthiocyclohexanone, and 2-phenylthio-2-cyclopentenone affords the corresponding (1S,2R)-2-phenylthiocycloalkanols in optically pure form and excellent diastereomeric excess.
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页码:399 / 400
页数:2
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