ON THE ORIGIN OF PI-FACIAL DIASTEREOSELECTIVITY IN NUCLEOPHILIC ADDITIONS TO CHIRAL CARBONYL-COMPOUNDS .1. ROTATIONAL PROFILES OF PROPIONALDEHYDE-1, CHLOROACETALDEHYDE-2, AND 2-CHLOROPROPIONALDEHYDE-3

被引：43

作者：

FRENKING, G

KOHLER, KF

REETZ, MT

机构：

[1] Fachbereich Chemie, Universität Marburg, D-3550 Marburg, Hans-Meerwein-Strasse

来源：

TETRAHEDRON | 1991年 / 47卷 / 43期

关键词：

D O I：

10.1016/S0040-4020(01)86504-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The conformational profiles for rotation around the C-C(= O) bond-alpha and the energy minimum conformations are calculated for propionaldehyde 1, chloroacetaldehyde 2, and 2-chloropropionaldehyde 3 at MP2/6-31G(d)//HF/6-31G(d). The energy level of the LUMO is calculated as a function of alpha for 1, 2, and 3 and discussed in relationship to the Felkin-Anh model.

引用

页码：8991 / 9004

页数：14

共 44 条

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