THE [ZR(6)X(18)H(5)](3-) IONS WITH X=CL, BR, AND RELATED SPECIES

被引：18

作者：

CHEN, LF ^{[1
]}

COTTON, FA ^{[1
]}

WOJTCZAK, WA ^{[1
]}

机构：

[1] TEXAS A&M UNIV,MOLEC STRUCT & BONDING LAB,COLLEGE STN,TX 77843

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 17期

关键词：

CLUSTERS; HYDRIDES; STRUCTURE ELUCIDATION; ZIRCONIUM COMPOUNDS;

D O I：

10.1002/anie.199518771

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new class of octahedral zirconium cluster compounds containing only halide and hydride ligands is described. These contain the anions [Zr6X18H4]4− or [Zr6X18H5]3− (shown on the right). The hydrogen atoms are randomly disordered on positions in or very near to the centers of all the triangular faces of the Zr6 octahedron according to X‐ray crystallography. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1877 / 1879

页数：3

共 9 条

[1] EMPTY OCTAHEDRAL HEXAZIRCONIUM CLUSTERS WITH ONLY 10 ELECTRONS, [ZR6X14(PR3)4]
COTTON, FA
FENG, XJ
SHANG, MY
WOJTCZAK, WA
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (08): : 1050 - 1053
[2] SYNTHESIS BY SPONTANEOUS SELF-ASSEMBLY OF METAL ATOM CLUSTERS OF ZIRCONIUM, NIOBIUM, AND TANTALUM
COTTON, FA
KIBALA, PA
ROTH, WJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (01) : 298 - 300
[3] PENTANUCLEAR ZIRCONIUM CLUSTERS WITH CHLORIDE, HYDRIDE, AND PHOSPHINE-LIGANDS
COTTON, FA
LU, J
SHANG, MY
WOJTCZAK, WA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (10) : 4364 - 4369
[4] THE ZR6CL12(PME2PH)6 MOLECULE REVISITED - A DIRECTED SYNTHESIS
COTTON, FA
WOJTCZAK, WA
[J]. INORGANICA CHIMICA ACTA, 1994, 223 (1-2) : 93 - 95
[5] COTTON FA, 1992, ANGEW CHEM, V104, P1117
[6] SOLUTION CHEMISTRY AND DERIVATIVES OF CENTERED ZIRCONIUM CHLORIDE CLUSTER PHASES
ROGEL, F
CORBETT, JD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (22) : 8198 - 8200
[7] SHELDRICK GM, 1993, FORTRAN 77 PROGRAM R
[8] TH6BR15H7-STABILIZATION OF A TH6BR12 CLUSTER BY 7 HYDROGEN-ATOMS
SIMON, A
BOTTCHER, F
COCKCROFT, JK
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (01): : 101 - 102
[9] SIMON A, 1991, ANGEW CHEM, V103, P79

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