BASE-INDUCED BRIDGE CLEAVAGE OF 1,5-DIMETHYL-7-OXABICYCLO[2.2.1]HEPT-5-ENE SYSTEMS

被引：12

作者：

ARJONA, O

CONDO, S

PLUMET, J

VISO, A

机构：

[1] Departamento de Química Orgánica I, Facultad de Química, Universidad Complutense

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 34期

关键词：

D O I：

10.1016/0040-4039(95)01167-G

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of 1,5-dimethyl-7-oxabicyclo[2.2.1]hept-5-enes 2 c-e with LDA produces good yields of hydroxy dienes 3 c-e through a novel and efficient bridge cleavage process; these dienes may undergo selective epoxidation to yield highly functionalized vinyl oxiranes such as 4.

引用

收藏

页码：6157 / 6158

页数：2

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