ENZYMES IN POLYMER CHEMISTRY .8. CHEMOENZYMATIC SYNTHESIS OF POLYMERIZABLE 11-METHACRYLOYL-AMINOUNDECANOIC ESTER OF 1-O-METHYL-ALPHA-D-GLUCOSE AND 3-O-METHYL-ALPHA-D-GLUCOSE IN 6-O-POSITION

被引：13

作者：

GEYER, U ^{[1
]}

KLEMM, D ^{[1
]}

PAVEL, K ^{[1
]}

RITTER, H ^{[1
]}

机构：

[1] UNIV GESAMTHSCH WUPPERTAL,FACHBEREICH ORGAN CHEM MAKROMOLEK CHEM 9,D-42097 WUPPERTAL,GERMANY

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 1995年 / 16卷 / 04期

关键词：

D O I：

10.1002/marc.1995.030160417

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The paper describes the regioselective esterification of a glucopyranoside and glucose derivative with 11-methacryloylaminoundecanoic acid in the presence of a lipase from Candida antarctica. The obtained modified sugar derivatives 6-O-(11-methacryloylaminoundecanoyl)-1-O-methyl- alpha-D-glucopyranoside (3a) and 6-O-(11-methacryloylaminoundecanoyl)-3-O-methyl-alpha-D-gluco-pyranose (3b) were polymerized radically with AIBN as initiator.

引用

页码：337 / 341

页数：5

共 23 条

[1] ENZYME CATALYZED PREPARATION OF 6-O-ACYLGLUCOPYRANOSIDES [J].

ADELHORST, K ;

BJORKLING, F ;

GODTFREDSEN, SE ;

KIRK, O .

SYNTHESIS-STUTTGART, 1990, (02) :112-115

[2]

[Anonymous], 1986, J AM CHEM SOC, V108, P5683

[3] ENZYMATIC DERIVATIZATION OF SACCHARIDES AND THEIR CHEMICAL POLYMERIZATION [J].

BLINKOVSKY, AM ;

DORDICK, JS .

TETRAHEDRON-ASYMMETRY, 1993, 4 (06) :1221-1228

[4] CHEMOENZYMATIC SYNTHESIS OF LINEAR POLY(SUCROSE ACRYLATE) - OPTIMIZATION OF ENZYME-ACTIVITY AND POLYMERIZATION CONDITIONS [J].

CHEN, XM ;

JOHNSON, A ;

DORDICK, JS ;

RETHWISCH, DG .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 1994, 195 (11) :3567-3578

[5]

GHORARE A, 1990, J CHEM SOC CHEM COMM, P134

[6] SYNTHESIS OF ACRYLIC ESTERS BY LIPASE [J].

IKEDA, I ;

TANAKA, J ;

SUZUKI, K .

TETRAHEDRON LETTERS, 1991, 32 (47) :6865-6866

[7]

IKEDA I, 1993, BIOTECHNOL BIOENG, V42, P7881

[8] CELLULASE-CATALYZED GLYCOSYLATION REACTIONS - SIMPLE ROUTE TOWARDS A HIGHLY SELECTIVE SYNTHESIS OF OLIGOSACCHARIDES [J].

KARTHAUS, O ;

SHODA, S ;

TAKANO, H ;

OBATA, K ;

KOBAYASHI, S .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1994, (13) :1851-1857

[9]

KUROKA H, 1994, MACROMOL RAPID COMM, V15, P507

[10] ASSEMBLY OF SYNTHETIC CELLULOSE-I [J].

LEE, JH ;

BROWN, RM ;

KUGA, S ;

SHODA, S ;

KOBAYASHI, S .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1994, 91 (16) :7425-7429

← 1 2 3 →