RHENIUM AND RUTHENIUM INDUCED RING CLOSING OLEFIN METATHESIS TO HYDROAZULENES

被引：34

作者：

SCHNEIDER, MF ^{[1
]}

JUNGA, H ^{[1
]}

BLECHERT, S ^{[1
]}

机构：

[1] TECH UNIV BERLIN,INST ORGAN CHEM,D-10623 BERLIN,GERMANY

来源：

TETRAHEDRON | 1995年 / 51卷 / 47期

关键词：

D O I：

10.1016/0040-4020(95)00822-P

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several highly functionalized diolefins cyclize to hydroazulenes via olefin metathesis catalyzed either by CH3ReO31 or by the ruthenium catalyst synthesized by Grubbs.(2) We demonstrate the superiority of the ruthenium catalyst.

引用

页码：13003 / 13014

页数：12

共 12 条

[1] INTRAMOLECULAR ALKYLATION OF CYCLOPENTENONES - A GENERAL-ROUTE TO CONJOINT RING-SYSTEMS [J].

ANTCZAK, K ;

KINGSTON, JF ;

ALWARD, SJ ;

FALLIS, AG .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1984, 62 (05) :829-837

[2]

CONNOLLY JD, 1991, DICT TERPENOIDS MONO, V1, P465

[3] DIMETHYLOXOSULFONIUM METHYLIDE ((CH3)2SOCH2) AND DIMETHYLSULFONIUM METHYLIDE ((CH3)2SCH2) FORMATION AND APPLICATION TO ORGANIC SYNTHESIS [J].

COREY, EJ ;

CHAYKOVSKY, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (06) :1353-+

[4] CATALYTIC RING-CLOSING METATHESIS OF FUNCTIONALIZED DIENES BY A RUTHENIUM CARBENE COMPLEX [J].

FU, GC ;

NGUYEN, ST ;

GRUBBS, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (21) :9856-9857

[5]

HERISSON JL, 1970, MAKROMOL CHEM, V141, P161

[6] SIMPLE AND EFFICIENT SYNTHESIS OF METHYLTRIOXORHENIUM (VII) - A GENERAL-METHOD [J].

HERRMANN, WA ;

KUHN, FE ;

FISCHER, RW ;

THIEL, WR ;

ROMAO, CC .

INORGANIC CHEMISTRY, 1992, 31 (21) :4431-4432

[7] A NEW APPROACH TO HYDROAZULENES VIA OLEFIN METATHESIS [J].

JUNGA, H ;

BLECHERT, S .

TETRAHEDRON LETTERS, 1993, 34 (23) :3731-3732

[8] A NOVEL-APPROACH TO THE ASYMMETRIC-SYNTHESIS OF MANZAMINE-A - CONSTRUCTION OF THE TETRACYCLIC ABCE RING-SYSTEM [J].

MARTIN, SF ;

LIAO, YS ;

WONG, YL ;

REIN, T .

TETRAHEDRON LETTERS, 1994, 35 (05) :691-694

[9] REDUCTIVE ALKYLATION OF ALPHA-EPOXYKETONES [J].

MCCHESNEY, JD ;

WYCPALEK, AF .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1971, (11) :542-+

[10] APPLICATION OF CARBONYL UMPOLUNG TO PROSTAGLANDIN SYNTHESIS .3. SYNTHESIS OF 11-DEOXY PROSTAGLANDIN SYNTHONS [J].

NOVAK, L ;

BAAN, G ;

MAROSFALVI, J ;

SZANTAY, C .

CHEMISCHE BERICHTE-RECUEIL, 1980, 113 (09) :2939-2949

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