PLANAR DEFORMATION OF AMORPHOUS POLY(ETHYLENE-TEREPHTHALATE) BY STRETCHING AND FORGING

被引:15
作者
GUAN, JY [1 ]
WANG, LH [1 ]
PORTER, RS [1 ]
机构
[1] UNIV MASSACHUSETTS,DEPT POLYMER SCI & ENGN,AMHERST,MA 01003
关键词
POLY(ETHYLENE TEREPHTHALATE); AMORPHOUS; PLANAR DEFORMATION OF; DEFORMATION OF PET BY STRETCHING AND FORGING; DRAWING TECHNIQUES AND DEFORMATION OF PET; CRYSTALLIZATION IN DRAWN PET;
D O I
10.1002/polb.1992.090300705
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The planar deformation of amorphous poly (ethylene terephthalate) (PET) was performed by stretching and by forging under comparable conditions at a series of constant temperatures, 80, 90, 100, and 110-degrees-C. The highest planar draw ratios of 4.5 X 4.5 and 3.5 X 3.5 were obtained by forging and stretching, respectively. Samples were studied before and after deformation by wide angle x-ray scattering (WAXS), differential scanning calorimetry (DSC), density measurements, and elastic recovery at 100-degrees-C. A distinct difference in efficiency of draw between these two techniques is found, as judged mainly by the strain-induced crystallization. The forging is more effective than stretching in achieving stabilized planar draw under comparable process conditions.
引用
收藏
页码:687 / 691
页数:5
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