CHEMISTRY OF AYURVEDIC CRUDE DRUGS .5. GUGGULU (RESIN FROM COMMIPHORA-MUKUL) .5. SOME NEW STEROIDAL COMPONENTS AND, STEREOCHEMISTRY OF GUGGULSTEROL-I AT C-20 AND C-22

被引：50

作者：

BAJAJ, AG ^{[1
]}

DEV, S ^{[1
]}

机构：

[1] MALTI CHEM RES CTR, VADODARA, INDIA

来源：

TETRAHEDRON | 1982年 / 38卷 / 19期

关键词：

D O I：

10.1016/0040-4020(82)85024-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

20.alpha.-Hydroxy-4-pregnen-3-one, 20.beta.-hydroxy-4-pregnen-3-one, 16.beta.-hydroxy-4,17(20)Z-pregnadien-3-one (4 ) and 16.alpha.-hydroxy-4-pregnen-3-one were isolated as new steroidal components of the gum-resin from C. mukul. A simple procedure for the synthesis of 4 is described. Chirality at C-20, C-22 in guggulsterol-I was clarified.

引用

页码：2949 / 2954

页数：6

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[21] STANDARDIZATION OF SILICIC ACID FOR CHROMATOGRAPHY [J].