CHEMICAL AND PHOTOCHEMICAL BEHAVIOR OF PHENOLIC ANTIOXIDANTS IN POLYMER STABILIZATION .1. A STATE-OF-THE-ART REPORT

被引:81
作者
POSPISIL, J
机构
[1] Institute of Macromolecular Chemistry, Czech Republic Academy of Sciences
关键词
D O I
10.1016/0141-3910(93)90209-2
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Phenols used as processing and long-term stabilizers of polymers are chemically very reactive systems. They transform via the respective phenoxyls. Characteristic transformation pathways, including the reactivities of the principal classes of transformation products, are analyzed using up-to-date knowledge of the topic.
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页码:217 / 232
页数:16
相关论文
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[1]  
Allen N.S., 1980, PHOTOCHEMISTRY DYED
[2]   RECENT ADVANCES IN THE PHOTOOXIDATION AND STABILIZATION OF POLYMERS [J].
ALLEN, NS .
CHEMICAL SOCIETY REVIEWS, 1986, 15 (03) :373-404
[3]   CHEMISTRY OF STABLE PHONOXY RADICALS [J].
ALTWICKE.ER .
CHEMICAL REVIEWS, 1967, 67 (05) :475-+
[4]   ELECTRON MAGNETIC RESONANCE OF PHENOXY RADICALS [J].
BECCONSALL, JK ;
CLOUGH, S ;
SCOTT, G .
TRANSACTIONS OF THE FARADAY SOCIETY, 1960, 56 (04) :459-472
[5]   QUINONE DEHYDROGENATION .3. OXIDATION OF 2,4-DI-T-BUTYLPHENOL [J].
BECKER, HD .
JOURNAL OF ORGANIC CHEMISTRY, 1969, 34 (05) :1198-&
[6]   SOME UNUSUAL OXIDATION-PRODUCTS OF 2,6-DI-TERT-BUTYL-4-METHYLPHENOL [J].
BENJAMIN, BM ;
RAAEN, VF ;
HAGAMAN, EW ;
BROWN, LL .
JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (15) :2986-2991
[7]  
BREDE O, 1990, 12TH P INT C ADV CON, P116
[8]   ZUM CHEMISMUS DER VIOLETTFARBUNG DES 4-METHYL--2.6-DI-TERT.-BUTYL-PHENOLS IN ALKALISCHEM MEDIUM [J].
BRIESKORN, CH ;
ULLMANN, K .
CHEMISCHE BERICHTE-RECUEIL, 1967, 100 (02) :618-+
[9]  
BRODILOVA J, 1986, J ANGEW MAKROMOL CHE, V161, P172
[10]   ANTIOXIDANTS AND STABILIZERS .54. EFFECT OF SELECTED TRANSFORMATION PRODUCTS OF PHENOLIC ANTIOXIDANTS ON TETRALIN OXIDATION AT 65 DEGREES C [J].
BUBEN, I ;
POSPISIL, J .
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1975, 40 (04) :987-998