DEPENDENCE OF THE MAGNETIC SUPEREXCHANGE ON THE CR...CR DISTANCE IN DINUCLEAR CHROMIUM(II) COMPLEXES

被引：43

作者：

BOSSEK, U

WIEGHARDT, K

NUBER, B

WEISS, J

机构：

[1] RUHR UNIV BOCHUM,LEHRSTUHL ANORGAN CHEMIE 1,POSTFACH 102148,W-4630 BOCHUM 1,GERMANY

[2] UNIV HEIDELBERG,INST ANORGAN CHEM,W-6900 HEIDELBERG,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 09期

关键词：

D O I：

10.1002/anie.199010551

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The spins of unpaired electrons in binuclear CrIII complexes containing the structural element A are coupled antiferromagnetically. Measurement of the temperature‐dependent susceptibilities showed that the contribution of this coupling is inversely proportional to the twelfth power of the intramolecular distance between the Cr ions (|J| ∼ r−12). (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1055 / 1057

页数：3

共 23 条

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