ORGANOTRANSITION-METAL COMPLEXES OF MULTIDENTATE LIGANDS .11. SYNTHESIS, STRUCTURE, AND REACTIVITY OF THE 1ST INTRAMOLECULAR COORDINATION COMPOUND WITH A WEAKLY BOUND ETA-2-ARENE

被引：40

作者：

SHIU, KB ^{[1
]}

CHOU, CC ^{[1
]}

WANG, SL ^{[1
]}

WEI, SC ^{[1
]}

机构：

[1] NATL TSING HUA UNIV,DEPT CHEM,HSINCHU 30043,TAIWAN

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 01期

关键词：

Arenes - Multidentate Ligands - Organotransition Metal Complexes - Thermolysis;

D O I：

10.1021/om00115a046

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thermolysis of (PhHCPzʹ2)Mo(CO)4 (1) in DME gives (PhHCPzʹ2)Mo(CO)3 (2) (Pzʹ = 3,5-dimethylpyrazol-1-yl); comparison of the structural details of the two compounds and the reactivity of 2 show that this compound is the first example containing an intramolecularly coordinated η2-arene ligand. © 1990, American Chemical Society. All rights reserved.

引用

页码：286 / 288

页数：3

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