ORGANOTRANSITION-METAL COMPLEXES OF MULTIDENTATE LIGANDS .11. SYNTHESIS, STRUCTURE, AND REACTIVITY OF THE 1ST INTRAMOLECULAR COORDINATION COMPOUND WITH A WEAKLY BOUND ETA-2-ARENE

被引：40

作者：

SHIU, KB ^{[1
]}

CHOU, CC ^{[1
]}

WANG, SL ^{[1
]}

WEI, SC ^{[1
]}

机构：

[1] NATL TSING HUA UNIV,DEPT CHEM,HSINCHU 30043,TAIWAN

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 01期

关键词：

Arenes - Multidentate Ligands - Organotransition Metal Complexes - Thermolysis;

D O I：

10.1021/om00115a046

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thermolysis of (PhHCPzʹ2)Mo(CO)4 (1) in DME gives (PhHCPzʹ2)Mo(CO)3 (2) (Pzʹ = 3,5-dimethylpyrazol-1-yl); comparison of the structural details of the two compounds and the reactivity of 2 show that this compound is the first example containing an intramolecularly coordinated η2-arene ligand. © 1990, American Chemical Society. All rights reserved.

引用

页码：286 / 288

页数：3

共 25 条

[21] ORGANOTRANSITION-METAL COMPLEXES OF MULTIDENTATE LIGANDS .6. ELECTRONIC AND STERIC INFLUENCES ON THE FORMATION OF ETA-2-ACYL COMPLEXES
SHIU, KB
LEE, LY
[J]. JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 1989, 36 (01) : 31 - 34
[22] ORGANOTRANSITION-METAL COMPLEXES OF MULTIDENTATE LIGANDS .4. FACILE FORMATION OF A HEAT-STABLE AND AIR-STABLE, 17-ELECTRON RADICAL, HYDRIDOTRIS(3,5-DIMETHYLPYRAZOL-1-YL)BORATE,MO(CO)3, AND A SULFUR-BRIDGED DIMER, [HYDRIDOTRIS(3,5-DIMETHYLPYRAZOL-1-YL)BORATE,MO(CO)2]2S
SHIU, KB
LEE, LY
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 348 (03) : 357 - 360
[23] ORGANOTRANSITION-METAL COMPLEXES OF MULTIDENTATES .2. SYNTHESIS AND ALLYL BROMINATION OF N,N-BIS(3,5-DIMETHYLPYRAZOL-1-YL)METHANE DERIVATIVES OF THE GROUP-VI METAL-CARBONYLS
SHIU, KB
CHANG, CJ
[J]. JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 1987, 34 (04) : 297 - 300
[24] ORGANOTRANSITION-METAL COMPLEXES OF MULTIDENTATE LIGANDS .7. POLYPYRAZOLYLAMINE COMPLEXES OF CHROMIUM(II), MOLYBDENUM(II), AND TUNGSTEN(II) - STEREOCHEMICALLY NONRIGID AND RIGID PSEUDOOCTAHEDRAL MOLECULES
SHIU, KB
LIOU, KS
CHENG, CP
FANG, BR
WANG, Y
LEE, GH
VONG, WJ
[J]. ORGANOMETALLICS, 1989, 8 (05) : 1219 - 1224
[25] SHIU KB, IN PRESS ORGANOMETAL

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