GAS-PHASE COLLISION-INDUCED DISSOCIATION OF HIGHLY EXCITED NO2

被引：8

作者：

BIELER, CR ^{[1
]}

SANOV, A ^{[1
]}

HUNTER, M ^{[1
]}

REISLER, H ^{[1
]}

机构：

[1] UNIV SO CALIF, DEPT CHEM, LOS ANGELES, CA 90089 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1994年 / 98卷 / 04期

关键词：

D O I：

10.1021/j100055a003

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The gas-phase collision-induced dissocation (CID) of highly excited NO2 with argon has been observed in a crossed beams experiment. The dissociation yield as a function of the initial NO2 excitation energy is reported. The structure of the CID signal is similar to that observed in the fluorescence excitation spectrum of NO2, and the scaling of energy transfer can be described by an exponential decay law. NO is detected state selectively using laser ionization, and state distributions are determined.

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页码：1058 / 1060

页数：3

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