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SYNTHESIS OF NOVEL TETRATHIAFULVALENE-BASED [3]PSEUDOCATENANES BY SELF-ASSEMBLY - PREVENTION OF TRANS/CIS ISOMERIZATION

被引：60
作者：
LI, ZT [1 ]
STEIN, PC [1 ]
SVENSTRUP, N [1 ]
LUND, KH [1 ]
BECHER, J [1 ]
机构：
[1] ODENSE UNIV,DEPT CHEM,DK-5230 ODENSE M,DENMARK
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 22期
关键词：
CATENANES; CROWN ETHERS; SELF-ASSEMBLY; TETRATHIAFULVALENES;
D O I：
10.1002/anie.199525241
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Four catenanes having a tetrathiafulvalene unit in the biscyclic macrocycle and cyclobis(paraquat‐p‐phenylene) in the second macrocycle are described. The TTF units locked inside the cyclophane cages do not isomerize even in the presence of trifluoroacetic acid. One of the four catenanes is shown on the right. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany
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页码：2524 / 2528
页数：5
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