OXIDATION AND OXIDATIVE CARBONYLATION OF METHANE AND ETHANE BY HEXAOXO-MU-PEROXODISULFATE(2-) ION IN AQUEOUS-MEDIUM - A MODEL FOR ALKANE OXIDATION THROUGH THE HYDROGEN-ATOM ABSTRACTION PATHWAY

被引：66

作者：

LIN, MR ^{[1
]}

SEN, AM ^{[1
]}

机构：

[1] PENN STATE UNIV, DEPT CHEM, UNIV PK, PA 16802 USA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 12期

关键词：

D O I：

10.1039/c39920000892

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In aqueous medium, at 105-115-degrees-C, SO4-. (generated from S2O8(2-)) was found to abstract a hydrogen atom from methane and ethane to form the corresponding alkyl radicals which could be trapped efficiently by carbon monoxide, the resultant acyl radicals being ultimately converted into the homologous carboxylic acids.

引用

页码：892 / 893

页数：2

共 24 条

[1] KINETICS OF THE CAPTURE OF METHYL RADICALS BY CARBON-MONOXIDE IN AQUEOUS-SOLUTION [J].