SYNTHESIS OF 1,5-DITHIO-D-GLUCOPYRANOSE AND SOME OF ITS BIOLOGICALLY RELEVANT DERIVATIVES

被引：26

作者：

JOSEPH, B ^{[1
]}

ROLLIN, P ^{[1
]}

机构：

[1] UNIV ORLEANS,LCBA,URA 499,BP 6759,F-45067 ORLEANS 2,FRANCE

来源：

JOURNAL OF CARBOHYDRATE CHEMISTRY | 1993年 / 12卷 / 06期

关键词：

D O I：

10.1080/07328309308019002

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

5-Thio-D-glucose was transformed into the l,5-dithio analog 5 through a sequence involving anomeric bromination followed by a Cerny hydrosulfurization reaction. The nucleophilic reactivity of this first representative of a new class of sugar mercaptans was investigated through the synthetic elaboration of some biologically relevant dithiosaccharides and particularly the first thia-analogs of glucosinolates 18 and 19.

引用

页码：719 / 729

页数：11

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