SYNTHESIS OF UNSATURATED LACTONES VIA PALLADIUM-CATALYZED CYCLIZATION OF ALKENOIC ACIDS

被引：190

作者：

LAROCK, RC

HIGHTOWER, TR

机构：

[1] Department of Chemistry, Iowa State University, Ames

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 20期

关键词：

D O I：

10.1021/jo00072a004

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Acyclic and cyclic, aliphatic or aromatic, 4- or 5-alkenoic acids cyclize in high yield to 5- or 6-membered unsaturated lactones using 5 mol % Pd (OAc) 2, 2 equiv of NaOAc, and 1 atm Of O2.

引用

页码：5298 / 5300

页数：3

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