SYNTHESIS OF [PW9O37)FE3-XNIX(OAC)3(](9+X)- (X=PREDOMINANTLY-1) AND OXIDATION CATALYSIS BY THE CATALYST PRECURSOR

被引：45

作者：

MIZUNO, N

HIROSE, T

TATEISHI, M

IWAMOTO, M

机构：

[1] Hokkaido Univ, Sapporo, Japan

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1994年 / 88卷 / 02期

关键词：

HETEROPOLYANION; KEGGIN-TYPE POLYANION; OXYGENATION; TRI-TRANSITION-METAL COMPLEX;

D O I：

10.1016/0304-5102(93)E0343-F

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Fe3-xNix-substituted Keggin-type heteropolyanion, [PW9O37{Fe3-xNix(OAc)3}](9+x)- (x = predominantly 1), was synthesized and characterized by elemental analysis, Mossbauer, H-1 NMR, magnetic moment, FAB mass, acid/base titration, and IR spectroscopy. The resulting catalyst precursor well catalyzed the selective oxidations of aldehydes, cyclohexene, and cyclohexane.

引用

页码：L125 / L131

页数：7

共 45 条

[1] DAWSON TYPE HETEROPOLYANIONS .1. MULTINUCLEAR (P-31, V-51, W-183) NMR STRUCTURAL INVESTIGATIONS OF OCTADECA(MOLYBDOTUNGSTOVANADO)DIPHOSPHATES ALPHA-1,2,3-[P2MM'2W15O62]N- (M, M' = MO, V, W) - SYNTHESES OF NEW RELATED-COMPOUNDS [J].